Abstract

Microbial fuel cells (MFCs) have recently attracted more attention in the context of sustainable energy production. They can be considered as a future solution for the treatment of organic wastes and the production of bioelectricity. However, the low output voltage and the low produced electricity limit their applications as energy supply systems. The scaling up of MFCs both by developing bigger reactors with multiple electrodes and by connecting several cells in stacked configurations is a valid solution for improving these performances. In this paper, the scaling up of a single air-cathode microbial fuel cell with an internal volume of 28 mL, has been studied to estimate how its performance can be improved (1523 mW/m3, at 0.139 mA). Four stacked configurations and a multi-electrode unit have been designed, developed, and tested. The stacked MFCs consist of 4 reactors (28 mL × 4) that are connected in series, parallel, series/parallel, and parallel/series modes. The multi-electrode unit consists of a bigger reactor (253 mL) with 4 anodes and 4 cathodes. The performance analysis has point ed out that the multi-electrode configuration shows the lowest performances in terms of volumetric power density equal to 471 mW/m3 at 0.345 mA and volumetric energy density of 624.2 Wh/m3. The stacked parallel/series configuration assures both the highest volumetric power density, equal to 2451 mW/m3 (274.6 µW) at 0.524 mA and the highest volumetric energy density, equal to 2742.0 Wh/m3. These results allow affirming that to increase the electric power output of MFCs, the stacked configuration is the optimal strategy from designing point of view.

Highlights

  • Microbial fuel cells (MFCs) can be considered as a future option for the treatment of organic wastes, bioremediation, and the recovery of bioenergy from wastes [1,2,3,4]

  • The multi-electrode configuration shows the worst performance; it produces a maximum volumetric power density equal to 388 mW/m3 (98 μW) at 0.313 mA

  • The multi-electrode MFC consists of 4 anodes and 4 cathodes connected in parallel mode and the stacked MFCs configurations consist of 4 MFCs connected in series, in parallel, series/parallel, and parallel/series modes

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Summary

Introduction

MFCs can be considered as a future option for the treatment of organic wastes, bioremediation, and the recovery of bioenergy from wastes [1,2,3,4]. MFCs employ exoelectrogen microorganisms to transform energy stored in the chemical bonds of organic compounds (as fuel) into electrical energy, catalyzing oxidation and reduction reactions in the area between two electrodes. Walter et al [5] studied the potential of scaling up a self-stratifying MFC operating in supercapacitive mode. They tested cells with different electrodes area

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