Inverse melting in a system with positive heats of formation

Abstract

Supersaturated body-centered-cubic Fe-W solid solutions with positive heats of formation were prepared by cosputtering and mechanical alloying over a wide concentration range. Upon annealing, these solid solutions were observed to undergo amorphization in the range of 20{endash}37 at.{percent} W. For Fe{sub 70}W{sub 30} and Fe{sub 67}W{sub 33} the transformation was polymorphous, indicating an inverse melting behavior. A thermodynamic analysis of the Fe-W system, which was carried out using the calculation-of-phase-diagrams method, supported that inverse melting is energetically possible in the Fe-W system. The results demonstrate that inverse melting can also occur in systems with positive heats of amorphous phase formation. {copyright} {ital 1997} {ital The American Physical Society}