Abstract

This introductory chapter provides an overview of stereoselectivity in organic synthesis. Given the importance of the three-dimensional structure of organic compounds, and the fact that all organic compounds arise as a result of a previous reaction or reaction sequence, it is not surprising that an area of chemistry which encompasses organic reactions and stereochemistry is central to organic chemistry. This book focuses on the area of stereoselective organic reactions, highlighting their usefulness in organic synthesis where appropriate. For the most part, it is concerned with reactions which involve the formation of tetrahedral carbon atoms within a molecular framework. The chapter then looks at diastereoselective reactions, enantioselective reactions, and stereospecific and stereoselective reactions.

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