Introduction

Abstract

Abstract Since the beginning of this century we have a rough understanding about the structure of atoms. They consist of a nucleus and electrons orbiting around this nucleus. We know that electrons occupy only certain discrete energy states. When they decay from a high-energy state to a low-energy state, they emit electromagnetic radiation. Usually, the low-energy state will be the ground state. In that case, the emitted radiation is called resonance radiation.1 Since the resonance photons have an energy that corresponds to the energy of the transition, they can easily be absorbed by other ground-state atoms. A ground-state atom that absorbs the resonance photon is excited to the upper state for some time and will eventually release the photon again. This absorption/reemission process can be repeated many times, until the photon finally escapes from the vapour. This process is called ‘radiation trapping’ (also known as ‘imprisonment of resonance radiation’, ‘radiative transfer of spectral lines’, ‘line transfer’, or ‘radiation diffusion’).