Abstract

Organic nonlinear optical chromophores with different number of N atoms were prepared and characterized. Their nonlinear optical character was studied both by theoretical calculation and second harmonic generation experiment. Chromophore ZJ1 showed us the largest d33 value of 87.5pm/V. More importantly, the photochemistry stability of the chromophores was also studied in details. Chromophores with N atoms in the conjugated system showed us better photochemistry stability than the traditional chromophores.

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