Introducing and performance evaluation of a novel Multi-Generation process for producing Power, fresh Water, oxygen and nitrogen integrated with liquefied natural gas regasification and carbon dioxide removal process

Abstract

The objective of this paper is to develop and evaluate a new integrated multigenerational system comprised of cryogenic air separation, hydrate-based desalination, combined cycle and oxyfuel power plants, carbon dioxide amine absorption, and transcritical carbon dioxide power cycle, employing liquefied natural gas cold energy. This integrated multi-generation system, applicable for liquefied natural gas importer terminals with access to seawater, produces approximately 2,533 MW net output power and 1,985 kg/h fresh water. In addition, this integrated multi-generation process produces 16,735,861 kg/h high-purity liquid oxygen (100 mol%), 4,773,633 kg/h liquid nitrogen with 99.71 mol% purity, more than 31,724,465 kg/h high-purity gaseous nitrogen (99.9 mol%), and 90,903,230 kg/h low-purity gaseous nitrogen (83.38 mol%). About 5907.3 MW of produced power is generated by liquefied natural gas expander. The performance of this system is evaluated by energetic methods. The results of energy analysis show the specific energy consumptions of the air separation products are 0.551 kW/kg and 1.93 kW/kg for liquid oxygen and nitrogen, respectively. Moreover, in the hydrate-based desalination subsystem, the specific energy consumption is 0.5 kW/m3 for produced pure water. The combined cycle power plant includes two gas turbines, three steam turbines, and a three-pressure level heat recovery steam generation. The thermal efficiencies of gas turbine cycles (Bryton), steam turbine cycles (Rankine) and combined power cycles are 26.3 %, 29.6 %, and 36.2 %, respectively. The flue gases from power plants enter the carbon dioxide amine absorption subsystem. The separated carbon dioxide is used as a working fluid to produce 372.1 MW power in transcritical carbon dioxide cycle. The results of energy analysis for carbon dioxide amine absorption subsystem show that the specific energy consumption, the ratio of captured carbon dioxide per unit mass of liquefied natural gas and the carbon dioxide removal efficiency are 6.60 kW/kg, 33.91 kg/tone, and 90.06 %, respectively. Approximately 2,905,000 kg/h of liquid carbon dioxide is obtained as the byproduct of this multi-generation process. Additionally, sensitivity analysis is conducted to determine key parameters influencing the main energetic indexes. Finally, the amount of attainable regasified natural gas reaches 257,523 tone/h by applying this multi-generation system with total 86 % energy efficiency.