Intrinsic Volume Changes of Self‐propagating Synthesis

Abstract

The final product(s) of self‐propagating synthesis are shown to be intrinsically denser than the starting reactants. This behavior results in intrinsic decreases in the sample volume that increase with both the heat of reaction and the adiabatic combustion temperature. Forming of liquid product(s) during reaction simply adds another intrinsic source of porosity, i.e. changes in volume on product solidification. Thus, obtaining fully dense bodies from self‐propagating synthesis requires a mechanism for reducing porosity, e.g. hot‐pressing.