Abstract

AbstractSedimentological and hydrochemical parameters of the River Piedra (north‐east Spain) were monitored every six months (from 1999 to 2012) at 24 sites, at which tablets were installed all along the river. The river water is of HCO3–SO4–Ca type and is notably influenced by inputs from upstream karstic springs. Tufa deposition was first detected 8 km downstream of these springs and greatly increased from there, primarily along the steeper stretch (i.e. within the Monasterio de Piedra Natural Park); then, deposition decreased through the most downstream stretch, with smaller ground water inputs. The spatial evolution of the tufa thickness, with parallel variations of PWP (Plummer, Wigley, Parkhurst) rates, was thus determined by the river water pCO2 which was controlled by ground water inputs and by the river bed slope. Five fluvial subenvironments and seven sedimentary facies were characterized. The water flow conditions are the primary factor responsible for the distinct deposition rates of facies, mainly through CO2‐outgassing. Stromatolites and moss‐tufa and alga‐tufa had the highest rates, whereas loose tufa formed in slow‐flowing water and tufa of spray areas had thinner deposition. A six‐month pattern in the deposition rate was detected through thickness measurements. That pattern was parallel to the seasonal PWP rates. The increased deposition during warm periods (spring and summer; mean: 5·08 mm) compared with cool periods (autumn and winter; mean: 2·77 mm) is linked chiefly to temperature, which controlled the seasonal changes in the physico‐chemical and biological processes; this finding is supported by a principal components analysis. Seasonal variations of insolation and day duration also contributed to such a deposition pattern. Large discharge events, which provoked erosion of tufa deposits and dilution of water, caused the reversal of the seasonal deposition rate pattern. Stromatolites are likely to preserve the most complete sedimentary record. Although tufas are a potentially sensitive record of climate‐related parameters, erosion is an intrinsic process that may overwhelm the effects of such parameters. This issue should be considered in palaeoclimatic studies based on the tufa record, particularly in semi‐arid conditions.

Highlights

  • The study of present-day tufa sedimentation in the fluvial environment has become a matter of great interest because of the ability of tufas to record environmental changes at different time scales

  • The principal components analysis (PCA) was performed with a dataset including all of the hydrochemical variables (10 analysed variables – temperature, pH, Ca, Mg, Na, K, Cl, SO4, alkalinity and conductivity – and four calculated variables – pCO2, SIc, total dissolved inorganic carbon (TDIC) and PWP), measured water velocity, mean monthly air temperature and discharge values

  • A mean deposition rate of 7Á86 mm yrÀ1 was measured from a total of 24 tablets set throughout the River Piedra from November 1999 to September 2012; this value is very similar to that obtained from 14 tablets within the area of the Natural Park for the first five years (7Á52 mm yrÀ1; Vazquez-Urbez et al, 2010), the latter study included the cave environment which had negligible deposition

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Summary

Introduction

The study of present-day tufa sedimentation in the fluvial environment has become a matter of great interest because of the ability of tufas to record environmental (for example, climatic and hydrological) changes at different time scales. The high-deposition rates of fluvial tufas (i.e. as much as 16 to 17Á5 mm yrÀ1; Pentecost, 1978; Vazquez-Urbez et al, 2010) makes possible the short-term monitoring of physical, chemical and biological parameters, which allows the factors that control the tufa sedimentation to be analyzed. The aim of these studies was to explain the significance of variations in sedimentological, hydrochemical and geochemical parameters, mainly in terms of climate and hydrological interpretation

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