Abstract
Thionin-sensitised intrazeolite photo-oxygenation of ( R)-(-)-α-phellandrene affords (1 S,5 R)-5-(1-methylethyl)-2-methylidene-3-cyclohexen-1-yl hydroperoxide as the major ene product. This can be easily reduced with triphenylphosphine to the natural product trans-yabunikkeol.
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