Abstract
The fluorescence and transient absorption spectra of N 2 -phenyl- N 1 -anthrylmethylpiperazine and N 2 - p -methoxyphenyl- N 1 -anthrylmethylpiperazine, a trichromophoric system D 2 -D 1 -A, were determined. They form an intramolecular ternary complex. In non-polar solvents, intersystem crossing through charge transfer to produce a localized triplet state is an important pathway of deactivation of the exciplex.
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