Abstract
Abstract The kinetics of photoinduced electron transfer and thermal recombination have been measured in a series of covalently linked donor-acceptor complexes. The molecules are based on pyrazolate-bridged iridium(I) dimers with pyridinium groups covalently bound to terminal phosphinite ligands. The driving-force dependence of the electron-transfer kinetics in one series agrees well with the predictions of the classical theory of electron transfer. The donor-acceptor electronic coupling, however, exhibits a sensitive and unexpected dependence on the nature of the bridge between the redox partners.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
