Abstract

The methylene-bridged Rh(I) dicarbonyl complex, [ Rh(bim) (CO) 2 + BPh 4 - ] ( 1) (bim = bis( N-methylimidazol-2-yl)methane), is an effective catalyst for the intramolecular hydroamination of selected ortho-alkynylanilines to give a range of benzo(dipyrroles).

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