Abstract
Tying the knot: In analogy to singlet carbenes, vinyl cations insert into CH bonds in a concerted intramolecular reaction, as shown by experimental investigations and quantum mechanical calculations. This reaction is useful for the synthesis of cyclopentane derivatives. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z504288_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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