Abstract

The intramolecular isotope effects in the decarboxylation of C13 and C14 carboxyl-labeled malonic and bromomalonic acids have been determined. The observed C13 effects are in agreement with the results of other investigators; the C14 effects are in partial agreement with earlier published results of one of the authors. The ratio of C14 to C13 effects is found to be near 3.6.

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