Abstract
Reaction of (cod)PtMe2 with 1 equiv and 2 equiv of the PN ligand (PN = o-Ph2PC6H4CH2OCH2C5H4N-2) (1) gave cis-(PN-κP:κN)PtMe2 (2) and cis-(PN-κP)2PtMe2 (3) respectively. The complex 2 underwent activation of the benzylic C–H bond in toluene at 110 °C to afford (PCN-κP:κC:κN)PtMe (4). Toluene solution of 3 was refluxed for 42 h in the presence of 2 equiv of the PN ligand to afford the C–O bond cleavage product cis-(PN-κP)(Ph2PC6H4CH2-κP:κC)PtMe (cis-5) along with cis-(PN-κP)(PCN-κP:κC)PtMe (cis-6).
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