Abstract
Abstract Two vibrational bands of an electronic transition of PtF occurring at 11 940 cm −1 and 12 496 cm −1 were recorded and analyzed. These transitions are identified as the (0,0) and (1,0) bands of an [11.9] Ω = 3/2 − X Ω = 3/2 electronic transition. Gas phase PtF was produced in a copper hollow cathode lined with platinum foil using a trace amount of SF 6 , and the spectrum was recorded at Doppler resolution by intracavity laser absorption spectroscopy. This work represents the first published spectroscopic data on PtF. Molecular constants for the ground and excited electronic states are presented.
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