Abstract

Abstract We systematically investigated the performance, i.e., thermally-induced voltage (Vcell) and discharge capacity (Qcell) per unit weight of the total active material, of the tertiary batteries made of transition metal hexacyanoferrates. Vcell and Qcell are reproduced by the values ( Vcell calc and Qcell calc) calculated from temperature (α) and charge (β) coefficients of the redox potential (V) of cathode and anode materials. Reflecting small -β of ZnHCF, Qcell for NCoF87/ZnHCF cell reaches 4.0 mAh/g between 20 ○C and 40 ○C.

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