Abstract
By an example of previously uncharacterized products obtained by alkylarenes radical chlorinationwas demonstrated that combination of various interpretation methods applied to the retention indices (RI) inthe gas chromatography on the standard nonpolar phases (comparison of RI of products, initialcompounds, characteristics of succession of the chromatographic elution of the structural isomers with theuse of estimation of molecular dynamic parameters, application of the additive schemes to RI calculation, and using of structural analogy CH3↔Cl for testing the results obtained) permitted unambiguous identification of the structure even without data of mass spectrometry.
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