Interplay between coherence-time undersampling and scattered light in two-dimensional electronic spectroscopy.

Abstract

Scanning pulse delays in multi-pulse non-linear optical spectroscopy experiments is a major contributor to lengthy data acquisition. Using large steps for the scan can significantly speed up the experiment. However, an improper choice of step length can cause distortions to the resulting spectra, especially if the light scattered on the sample is mixed into the signal. In this work, we identify potential sources of such distortions and suggest appropriate countermeasures to avoid them while maintaining a faster data collection.