Internal shorting and fuel loss of a low temperature solid oxide fuel cell with SDC electrolyte

Abstract

Abstract A solid oxide fuel cell with Sm0.2Ce0.8O1.9 (SDC) electrolyte of 10 μm in thickness and Ni–SDC anode of 15 μm in thickness on a 0.8 mm thick Ni–YSZ cermet substrate was fabricated by tape casting, screen printing and co-firing. A composite cathode, 75 wt.% Sm0.5Sr0.5CoO3 (SSCo) + 25 wt.% SDC, approximately 50 μm in thickness, was printed on the co-fired half-cell, and sintered at 950 °C. The cell showed a high electrochemical performance at temperatures ranging from 500 to 650 °C. Peak power density of 545 mW cm−2 at 600 °C was obtained. However, the cell exhibited severe internal shorting due to the mixed conductivity of the SDC electrolyte. Both the amount of water collected from the anode outlet and the open circuit voltage (OCV) indicated that the internal shorting current could reach 0.85 A cm−2 or more at 600 °C. Zr content inclusions were found at the surface and in the cross-section of the SDC electrolyte, which could be one of the reasons for reduced OCV and oxygen ionic conductivity. Fuel loss due to internal shorting of the thin SDC electrolyte cell becomes a significant concern when it is used in applications requiring high fuel utilization and electrical efficiency.