Abstract
The molecular structure and internal rotation of hydrogen peroxide are briefly reviewed in terms of recent data. By a statistical method, the thermodynamic properties are evaluated. The partition function for the internal rotation is obtained from the summation of experimental internal rotation energy levels. Based on the selected Δ H ° f (298.15 K) values, Δ H ° f , Δ G f , and log K f in the temperature range 0 to 1500 K are derived. The internal rotation contributions to C ° p and S ° are discussed in terms of earlier calculations.
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