Internal interface engineering of yolk-shell structure toward fast and robust potassium storage

Abstract

Advanced anode materials with stable and fast K-ion storage behavior are of great significance for potassium-ion batteries (PIBs) toward large-scale applications, while it still remains a big challenging due to their intrinsic poor conductivity and large volume variation during cycles. Herein, we develop an internal interfacial engineering by encapsulating core-shell NiS2@C nanoparticles within MOF-derived hollow carbon shell for superior PIB anodes. As-prepared yolk-shell NiS2@C@C composite integrates the structure superiority of abundant interior void space, outer protective carbon shell and internal conductive carbon layer. Comprehensive experimental and theoretical methods illuminate that internal NiS2/C interface is conductive to boost charge transport kinetics, enhance pseudocapacitive behavior, and mitigate mechanical stress in outer carbon shell. As a result, it manifests an ultrahigh capacity of 481 mA h g−1 at 0.2 A g−1, and guarantees the rate capability of 306 mA h g−1 at 20 A g−1. Moreover, it presents excellent cycle stability (358 mA h g−1 after 1600 cycles at 1 A g−1), which is extremely competitive among the best reported conversion anodes for PIBs.