Abstract

AbstractIn addition to the elimination of C6H5· and C7H7·, 2,8‐dimethyl‐10‐phenyl‐ and 10‐(p‐tolyl)‐phenothiaphosphines lost C6H5S· and C7H7S·, respectively from high internal energy molecular ions, while the low internal energy ions eliminated C6H5PH and C7H7PH, respectively. 2,8‐Dimethyl‐10‐phenylphenoxaphosphine lost C6H5·, C6H5P and C6H5PH· both in the source and in the first field‐free region, but the expulsion of C6H5O· was not observed.

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