Abstract
The transients detected during flash photolysis of chlorocuparate(I) complexes suggest the appearance of at least two intermediate complex species. They are formed consecutively and decay in parallel reactions. The dependences of the transients on the concentrations of the components make it possible to put forward a mechanism in which the equilibrium constant and the reaction rate constant as well as the apparent kinetic orders can be estimated.
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More From: Journal of Photochemistry & Photobiology, A: Chemistry
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