Abstract

Intermediate range structures of organic-inorganic mixed superionic conductor glasses were investigated by low-angle neutron diffraction and small-angle neutron scattering (SANS) experiments. Significant small angle scatterings were observed in the glasses composed of AgI-CsI-deuterized-tetramethylammonium iodides. The fractal dimension D f was estimated from the plot of the log I(q) vs. Log q; it was 0.39 above q c and 2.8 below, where q c was a cross-over wavelength of q c ∼ 0.02−0.05 A ̊ − 1 . This result strongly supports the existence of percolation clusters in the organic-inorganic mixed superionic conductor glasses, which has been expected from ionic conductivity measurements.

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