Intermediate Exciton-Phonon Coupling in Tetracene

Abstract

Polarized absorption spectra of tetracene (naphthacene) single crystals have been investigated between 300 and 13 K, with particular emphasis on the b -polarized spectrum. The low energy tails of the a - and b -polarized first absorption bands are expressed by the Urbach rule with the steepness coefficients σ a ′ =1.37 ±0.12, σ b ′ =1.58 ±0.13, with which possibility of self-trapping of excitons is discussed along with the dimensionality of tetracene crystals. The exciton-phonon coupling constants are found to be g a =1.09 ±0.1 and g b =0.95 ±0.08, consistent with luminescence experiments which show that excitons in tetracene are self-trapped very shallowly. The line halfwidth, the oscillator strength of the first and the second absorption bands, refractive indices, and surface exciton structure are briefly discussed.