Interlaminar properties of GFRP laminates toughened by CNTs buckypaper interlayer

Abstract

The interlaminar property is essential to the application of fiber reinforced composites for the overall performance. For the purpose of enhancing the interlaminar properties, the unidirectional Glass Fibre Reinforced Plastics (GFRP) laminates were fabricated by adding carbon nanotubes (CNTs) buckypaper to the mid-plane layers under different curing pressures (1 MPa, 2 MPa, 3 MPa). In order to study the enhancement mechanism of the CNTs buckypaper, a series of experiments were designed and conducted based on double cantilever beam (DCB), end notch flexure (ENF) and interlaminar shear strength (ILSS) tests followed by scanning electron microscope (SEM) examination to study the surfaces of the specimens. It was observed that the modes I and II interlaminar fracture toughness of GFRP embedded with CNTs buckypaper were relatively higher than those without CNTs buckypaper. Considerable improvements in interlaminar shear strength of the laminates were obtained with the integration of the CNTs buckypaper between the interlayers. The micro-structure of the enhanced mixed interface of fiber-resin-CNTs responsible for interlaminar strengthening was further studied with the help of SEM. It was found that the higher curing pressure could increase the inter-diffusion of the resin and CNTs offering a stronger interfacial adhesion. The interlaminar characteristics of the specimens cured at 2 MPa pressure were found to be relatively superior with optimal interlaminar fracture toughness and interlaminar shear strength.