Interlaminar fracture of CF/EP composite containing a dual-component microencapsulated self-healant

Abstract

We present an experimental study of the self-healing ability of carbon fibre/epoxy (CF/EP) composite laminates with microencapsulated epoxy and its hardener (mercaptan) as a healing agent. Epoxy- and hardener-loaded microcapsules (average size large: 123μm; small: 65μm) were prepared by in situ polymerisation in an oil-in-water emulsion and were dry-dispersed at the ratio 1:1 on the surface of unidirectional carbon fabric layer. The CF/EP laminates were fabricated using a vacuum-assisted resin infusion (VARI) process. Width-tapered double cantilever beam (WTDCB) specimens were used to measure mode-I interlaminar fracture toughness of the CF/EP composites with a pre-crack in the centre plane where the microcapsules were placed. Incorporation of the dual-component healant stored in the fragile microcapsules provided the laminates with healing capability on delamination damage by recovering as much as 80% of its fracture toughness. It was also observed that the recovery of fracture toughness was directly correlated with the amount of healant covering the fracture plane, with the highest healing efficiency obtained for the laminate with large capsules.