Abstract
AbstractA central problem in quantum mechanics is the calculation of the overlap, that is, the scalar product between two quantum states. In the semiclassical limit (Bohr's correspondence principle) we visualize this quantity as the area of overlap between two bands in phase space. In the case of more than one overlap the contributing amplitudes have to be combined with a phase difference again determined by an area in phase space. In this sense the familiar double‐slit interference experiment is generalized to an interference in phase space. We derive this concept by the WKB approximation, illustrate it by the example of Franck‐Condon transitions in diatomic molecules, and compare it with and contrast it to Wigner's concept of pseudo‐probabilities in phase space.
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