Abstract

The CO+ (A → X) fluorescence following the 1s → π* resonant excitation of the CO molecule and subsequent Auger decay has been investigated. The energy dependencies of the angular distribution parameters for the A 2Π(ν′) photoelectrons and for the subsequent A 2Π(ν′) → X 2Σ+(ν′′) fluorescence in the vicinity of the C*O and CO* resonances are predicted theoretically. These energy dependencies are due to the electronic states interference and lifetime vibrational interference. In order to test our predictions experimentally, polarization analysis of the CO+(A–X) fluorescence has been performed by photon-induced fluorescence spectroscopy.

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