Interfacial performance enhancement of carbon fiber/epoxy composites by a two-step surface treatment

Abstract

Carbon fiber-reinforced polymer composites (CFRPs) have many features, such as lightweight, high specific strength, and excellent chemical resistance. However, the adhesion at the interface of the CFRPs, which are composed of fiber and resin, is poor. Thus, de-lamination and interfacial peeling occur, and the mechanical properties, such as intrinsic strength and rigidity, decrease. Fiber surface modification by plasma and silane coupling treatments has attracted much attention to improve these properties. In this study, argon and oxygen mixed gas plasma treatment was used as pretreatment to introduce hydroxyl group on the fiber surface. This method was utilized to improve the adhesion between the fiber and resin. A silane coupling treatment was conducted to bond the carbon fiber and epoxy resin by chemical covalent bonding. The effect of silane coupling treatment on the interfacial property of CFRPs was investigated. Elemental analysis of the surface modified carbon fiber was explored through energy dispersive X-ray spectrometry. The functional groups of different carbon fiber surfaces were analyzed through X-ray photoelectron spectroscopy. The wettability of the treated carbon fiber was examined with a contact angle meter. The interlaminar shear strength was determined with a short beam method.