Interfacial Microstructure and Bonding Strength of Copper Cladding Aluminum Rods Fabricated by Horizontal Core-Filling Continuous Casting

Abstract

Copper cladding aluminum (CCA) rods with a diameter of 30 mm and a sheath thickness of 3 mm were fabricated by horizontal core-filling continuous casting (HCFC) technology. The microstructure and morphology, distribution of chemical components, and phase composition of the interface between Cu and Al were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), and energy dispersive spectrometer (EDS). The formation mechanism of the interface and the effects of key processing parameters, e.g., aluminum casting temperature, secondary cooling intensity, and mean withdrawing speed on the interfacial microstructure and bonding strength were investigated. The results show that the CCA rod has a multilayered interface, which is composed of three sublayers—sublayer I is Cu9Al4 layer, sublayer II is CuAl2 layer, and sublayer III is composed of α-Al/CuAl2 pseudo eutectic. The thickness of sublayer III, which occupies 92 to 99 pct of the total thickness of the interface, is much larger than the thicknesses of sublayers I and II. However, the interfacial bonding strength is dominated by the thicknesses of sublayers I and II; i.e., the bonding strength decreases with the rise of the thicknesses of sublayers I and II. When raising the aluminum casting temperature, the total thickness of the interface increases while the thicknesses of sublayers I and II decrease and the bonding strength increases. Either augmenting the secondary cooling intensity or increasing the mean withdrawing speed results in the decrease in both total thickness of the interface and the thicknesses of sublayers I and II, and an increase in the interfacial bonding strength. The CCA rod with the largest interfacial bonding strength of 67.9 ± 0.5 MPa was fabricated under such processing parameters as copper casting temperature 1503 K (1230 °C), aluminum casting temperature 1063 K (790 °C), primary cooling water flux 600 L/h, secondary cooling water flux 700 L/h, and mean withdrawing speed 87 mm/min. The total thickness of the interface of the CCA rod fabricated under the preceding processing parameters is about 75 μm, while the thicknesses of sublayers I and II are about 1.1 and 0.1 μm, respectively.