Abstract
The adhesion tensions, τ, on polytetrafluoroethylene and on dichlorodimethylsilane-treated glass, were obtained as a function of composition for three binary mixtures of polyethers, a polyether + water solution, and a polydimethylsiloxane + tetralin solution. From these, the solid/liquid interfacial tensions γSL were deduced and found to be in good agreement with those calculated using the Prigogine theory. It was also concluded that the replacement of the gas phase by a low-energy solid did not result in any substantial reorganization of the polar mixtures at the interface.
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