Abstract
TiO2 has been widely used as an n-type overlayer, simultaneously serving as a protective layer for photocathodes. However, the photovoltage generated from a TiO2 junction with p-type absorbers, such as p-Si, Sb2Se3, SnS, and Cu2O, is insufficient. We report a dipole reorientation strategy to overcome this limitation by inserting a polyethylenimine ethoxylated (PEIE) layer between a p-type absorber and TiO2. Furthermore, we demonstrate that the PEIE dipole orientation can be rearranged by increasing the layer thickness, leading to an upward shift of the TiO2 band edge. The magnitude of band shift induced by the dipole effect depends on the TiO2 layer thickness. Using this approach, the onset potential was significantly improved to 0.5 V versus the reversible hydrogen electrode (VRHE) in a p-Si/PEIE/TiO2/Pt device. The versatility of the effective dipole reorientation strategy was demonstrated by application to a range of TiO2-protected heterojunction photocathodes based on Sb2Se3, Cu2O, and SnS.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
