Abstract

Due to their excellent thermal stability and ideal bandgap, metal halide inorganic perovskite based solar cells (PSCs) with inverted structure are considered as an excellent choice for perovskite/silicon tandem solar cells. However, the power conversion efficiency (PCE) of inverted inorganic PSCs still lags far behind that of conventional n-i-p PSCs due to interfacial energy level mismatch and high nonradiative charge recombination. Herein, the performance of inverted PSCs was significantly improved by interfacial engineering of CsPbI3-x Brx films with 2-mercapto-1-methylimidazole (MMI). It is found that the mercapto group can preferably react with the undercoordinated Pb2+ from perovskite by forming Pb-S bonds, which appreciably reduces the surface trap density. Moreover, MMI modification results in a better energy level alignment with the electron transporting material, promoting carrier transfer and reducing voltage deficit. The above combination results in an open circuit voltage enhancement by 120mV, yielding a champion PCE of 20.6% for 0.09 cm2 area and 17.3% for 1 cm2 area. Furthermore, the ambient, operational and heat stabilities of inorganic PSCs with MMI modification are also greatly improved. Our work demonstrates a simple but effective approach for fabricating highly efficient and stable inverted inorganic PSCs. This article is protected by copyright. All rights reserved.

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