Abstract
AbstractCalix[4]pyrrole liquid membrane electrodes display a potentiometric response towards the neutral form of phenol derivatives. They do not respond towards the corresponding anionic forms. The mechanism of the generation of the potentiometric signal relies on: (1) The creation of supramolecular complex calix[4]pyrrolenitrophenol at the organic/aqueous interface; (2) The increasing of the acidity of OH group from nitrophenol molecules due to formation of hydrogen bond between calix[4]pyrrolenitrophenol at the interface; (3) The dissociation of the OH group from calix[4]pyrrolenitrophenol complex and the ejection of H+ to the aqueous layer adjusted to the membrane organic phase boundary. The sensitivity and selectivity of the calix[4]pyrrole liquid membrane electrodes are governed by the lipophilicity and acidity of the phenolic guests. Also, the affinity to create a hydrogen bond between the host and the target molecule is a parameter which has a strong influence on the phenomena studied.
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