Interface engineering of Ce/La-doped hydrochar-supported nickel catalysts for enhanced tar reforming performance at low temperature

Abstract

Catalytic reforming of biomass tar to syngas-especially under mild temperature-is an attractive albeit elusive route, necessitating the manufacture of highly efficient catalysts, in particular, from inexpensive, sustainable, and renewable resources as a prerequisite. Two interface-engineering strategies, including one-pot hydrothermal carbonization (HTC) approach and two-step HTC-impregnation method, were applied to fabricate a series of Ce/La-doped hydrochar-supported nickel catalysts, employing pinewood sawdust-derived hydrochar as the support, nickel as the active sites, and Ce or La as the promoter species. After the optimization of synthetic variables and operation conditions, the Ni0.1/Ce0.05-HC catalysts prepared by the two-step HTC-impregnation method simultaneously exhibited boosted activity, selectivity and recyclability than the Ni/HC counterpart without Ce addition as well as reported state-of-the-art catalysts in steam reforming of biomass tar at a low temperature of 600 °C. This exceptional catalytic performance was mainly attributed to the modulation of geometric structure and electronic structure of the exposed active sites by appropriate inclusion of cerium on the hydrochar-based nickel catalyst, which favored the water-gas shift, boudouard reaction and coke gasification, thereby imparting the materials with remarkable resistance against metal sintering and coke deposition during the steam reforming process. The result in this work underscores that the controlled interface between Ni species and hydrochar support by addition of Ce, which pertain to the hydrothermal processing technique, is a promising blueprint toward effective fuel production from waste biomass.