Interdiffusion in the Ni-Cr-Co-Mo system at 1300/sup 0/C

Abstract

Interdiffusion was investigated with solid-solid diffusion couples in the ..cap alpha.. (fcc) region of the quaternary Ni-Cr-Co-Mo system at 1300/sup 0/C for the determination of diffusion paths and diffusional interactions among the components. The concentration profiles for a given couple exhibited a common cross-over composition, Y/sub c/, which reflected the relative depths of diffusion in the terminal alloys. Interdiffusion fluxes were calculated directly from the concentration profiles and the quaternary interdiffusion coefficients were calculated at selected compositions. Ni and Co exhibited up-hill diffusion against their individual concentration gradients in a direction opposite to the interdiffusion of Cr. Quaternary diffusion paths were presented as a set of partial diffusion paths on the basis of relative concentration variables.