Abstract
The electrochemical reduction of CrOCl in NaClO 4/PC or LiClO 4/PC solutions is irreversible. At low current, it is controlled by stoichiometry and by diffusion of alkali metals. Formation of an unstable intercalation compound followed by its decomposition to LiCl (or NaCl) and oxide CrO is supposed. This was confirmed by chemical lithiation of CrOCl in Li solution in liquid NH 3.
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