Abstract
The mixed intercalates of the type VOSO 4·(2 − x)C p · xC q have been prepared by reaction of unhydrated layered VOSO 4 with liquid binary mixtures of the aliphatic alcohols. Symbols C p and C q mark two different unbranched primary aliphatic alcohols, p and q are numbers of carbon atoms in their molecules ( p< q). For q= p+1 the value of x changes continuously in the interval 〈0–2〉. For q > p + 2 these values range in intervals 〈0–0.05〉, 〈0.9–1.1〉 and (1.75−2). Relations between basal spacings of the formed layered complexes and their composition and the composition of the liquid alcohol (C 2 to C 7) mixtures were studied for fifteen systems. The schematic explanation of the arrangement of the alcohol molecules in van der Waal's gap is proposed.
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