Interactions of metal ions with monoaza crown ethers A15C5 and A18C6 carrying dansyl fluorophore as pendant in acetonitrile solution

Abstract

The influence of metal cations Li +, Na +, K +, Cs +, Mg 2+, Ca 2+, Sr 2+, Ba 2+, Co 2+, Ni 2+, Cu 2+, Zn 2+, Pb 2+ and Al 3+ on the spectroscopic properties of the dansyl (1-dimethylaminonaphthalene-5-sulfonyl) group covalently linked to monoaza crown ethers 1-aza-15-crown-5 (1,4,7,10,-tetraoxa-13-azacyclopentadecane) (A15C5) and 1-aza-crown-6 (1,4,7,10,13-pentaoxa-16-azacyclooctadecane) (A18C6) was investigated by means of absorption and emission spectrophotometry. Interaction of the alkali metal ions with both fluoroionophores is weak, while alkaline earth metal ions interact strongly causing 50 and 85% quenching of dansyl fluorescence of N-(5-dimethylamine-1-naphthalenesulfonylo)-1,4,7,10,-tetraoxa-13-azacyclopentadecane (A15C5-Dns) and N-(5-dimethylamine-1-naphthalenesulfonylo)-1,4,7,10,13-pentaoxa-16-azacyclooctadecane (A18C6-Dns), respectively. The Cu 2+, Pb 2+ and Al 3+ cations interact very strongly with dansyl chromophore, causing a major change in absorption spectrum of the chromophore and forming non-fluorescent complexes. The Co 2+, Ni 2+, Zn 2+, Mg 2+ cations interact moderately with both fluoroionophores causing quenching of dansyl fluorescence by several percent only.