Abstract
The complex formation between mercury(II) and selected sodium thiolates and corresponding thiols in dilute pyridine solution, and between silver(I) and selected organic sulfides in dilute pyridine and DMSO solutions, was investigated by electrochemical and calorimetric measurements. The stability constants and heats for the stepwise complex formation were determined, and the complex formation entropies were calculated from these. The results are in close agreement with the tendencies which have been found for the coordination behaviour of organic chalcogen ligands towards mercury(II) and silver(I) in other solvent systems, and the solid state.
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