Abstract
Tin (IV) chloride reacts with sulfolane (S) to form a cis-octahedral adduct SnCl4·S2. Solutions of lithium chloride and tin (IV) chloride in sulfolane contain the complex ions SnCl5− and SnCl62− at 1∶1 and 2∶1 mole ratios of constituents, respectively. The complexes are characterized by conductimetry and by Mossbauer, IR, and Raman spectroscopy.
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