Abstract
The interaction between the fluorinated alcohols RFOH (RF=(CF3)2CH and (CF3)3C) and rhenium hydride (η5-C5Me5)ReH(CO)(NO) in hexane and liquid freon was studied in a wide temperature range by IR and1H NMR methods, respectively. The formation of hydrogen-bonded complexes of two types, ReH...HORF and NO...HORF, was established. The hydride signal in the1H NMR spectra at 96 K splits into two signals (at δ=−7.54 and −8.87) corresponding to the free ReH and the ReH...HO complex, respectively.
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