Abstract
The force between two charged planar surfaces containing an electrolyte solution is calculated. The calculation is done for a 1-1 electrolyte with size-asymmetric ions using a Modified Gouy-Chapman theory. It is shown that at least part of the explanation for the sharp rise in the force between charged surfaces at small separations seen in experimental data may be related to finite-sized ion effects in the double layer. An interesting effect of size-asymmetric ions is the prediction of a force between uncharged surfaces.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.