Abstract
Abstract Adducts formed by the dinuclear complexes [Cu2(2,6-DMB)4(H2O)2], (I) and [Cu2(2,6-DMB)2-(O2CCH3)2(H2O)2], (II) (2,6-DMB = 2,6-dimethoxybenzoate) with nitrogenous bases [pyridine (py), 4-ethylpyridine (4-Etpy), pyrazine (pz), 2-methylpyrazine (2-Mepz), imidazole (im), l-methylimidazole (1-Meim) and 2-phenylimidazole (2-Phim)] have been synthesized and characterized. Starting with II, only one adduct, [Cu2(2,6-DMB)2(O2CCH3)2(2-Phim)2J, was obtained. In the other cases, starting with either I or II, monomeric compounds containing two 2,6-DMB ligands and one or two base molecules were isolated. The structure of these compounds consists, basically, of tetragonal copper(II) chromophores involving metal coordination by monodentate carboxyl groups and nitrogen atoms in the plane, with water molecules, when present, as axial donors.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
