Interaction of end-gas autoignition and cold wall in closed chamber

Abstract

The presence of cold walls in spark-ignition (SI) engines could induce the interaction with end-gas autoignition. This interaction is numerically studied in the current work considering detailed chemistry and transport, with emphasis on near-wall flame structures and dynamics, as well as autoignition-affected wall heat flux. Two alternative fuels, hydrogen, and dimethyl ether (DME), are considered. In hydrogen/air mixtures, autoignition first develops in the end-gas and leaves an unburnt near-wall region. The combustion mode in this region then sequentially behaves as spontaneous ignition, laminar flame, and low-to-intermediate temperature reaction. Correspondingly, the contribution of diffusion and convection in the energy budget respectively increases and decreases as the reaction front moves towards the wall. End-gas autoignition also introduces strong pressure waves propagating back-and-forth, which subsequently lead to multiple local maxima on the temporal evolution of wall heat flux. Consequently, the maximum wall heat flux no longer changes monotonically with both the wall temperature and the quenching distance. Furthermore, the role of low-temperature chemistry (LTC) is studied using DME/air mixtures, which exhibits typical multi-stage heat release and Negative Temperature Coefficient (NTC) behaviors. It is also noted that, the influence of pressure wave is minimal when the unburnt mixtures have relatively low energy density, such as at off-stoichiometric conditions and/or lower initial pressures. Specifically: consistent to distinct three-stage homogeneous ignition at certain fuel-lean conditions (ϕ = 0.25) and intermediate initial temperature (typically around T0 = 600–750 K), in the corresponding 1D case three-stage end-gas autoignition respectively evolves into the near-wall cool, warm and hot flame; in the case at relatively low initial pressures, only the first-stage autoignition occurs in the end-gas, and as such LTC slightly increases the wall heat flux and advances flame quenching. As the reactivity of unburnt mixtures becomes higher, LTC and HTC respectively introduce strong and weak knocking combustion. Multiple weak and strong local maxima are observed in the temporal evolution of wall heat flux, both of which changes non-monotonically with the wall temperature.