Abstract
The interaction of binary solid solutions with binary gallium eutectics is studied in situ by X-ray diffraction using synchrotron radiation to reveal the sequence of phase formation for the elements that leave a solid solution and a eutectic during the formation of the first intermetallic phase. A comparison of the chemical interactions of the solid solution of tin in copper with the gallium-indium eutectic, the solid solution of indium in copper with the gallium-tin eutectic, and the solid solution of bismuth in copper with these eutectics shows that phase formation during interaction depends on the state of the element (liquid or solid).
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