Interaction of coal and oil in confined pyrolysis experiments: Insight from the yield and composition of gas hydrocarbons

Abstract

Isothermal pyrolysis experiments were performed for coal alone, oil alone and coal plus oil with oil/coal ratios ranging from 0.0065 to 0.1995 at 305 °C and 50 MPa for 72 h in confined systems (gold capsules). The results of these experiments reveal the interaction between coal and oil, demonstrating that oil retards the generation of gas hydrocarbons from coal cracking while coal accelerates oil cracking into gas hydrocarbons. The yields of gas hydrocarbons vary greater with oil/coal ratio in the experiments of coal B plus oil than coal A plus oil because coal A has a higher HI value than does coal B. Oil cracking rate could increase by up to 10 or even higher times in the experiments of coal plus oil compared with oil alone, deduced from the yields and chemical compositions of gas hydrocarbons. This result suggests that gas hydrocarbons, especially wet gases were largely generated from the cracking of oil or extractable bitumen in the experiments of coal plus oil with oil/coal ratio higher than 0.1.