Abstract
The interaction of butadiene with trimethylvinylsilane over a nickel chloride catalytic system in the presence of an organoaluminum Lewis acid and triphenylphosphine proceeds by telomerization and results in the formation of telomer homologs of general formula (CH 3CHCHCH 2) nCSi(CH 3) 3CH 2, n = 1–5. The reaction is accompanied by the formation of a dimer of trimethylvinylsilane 2,4-bis(trimethylsilyl)-1-butene (ca. 5–15%).
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